Corporate Social Responsibility Acme Charity - 1663 Words

AcMe Charity of BC is a provincial leader in promoting equal access for recent immigrants wishing to enter the job market in the province. AcMe Charity s seasonal events are well attended. For continued success, synergistic relationships need to be fostered. For the upcoming event: Celebrating CSR†, it is important to carefully review The Starbucks Corporation prior to inviting them to this AcMe Charity event. Corporate Social Responsibility can be defined as a company’s social performance and the impacts of the company on its internal and external stakeholders, including: customers, suppliers, employees, communities, government and the environment. *** To be socially responsible, the company has to demonstrate a view to improve society because it is the â€Å"right thing to do† beyond its legal and economic considerations.*** Does Starbucks’ actually go beyond these considerations? Howard Schultz, Chairman, President and CEO of Starbucks would like to think so. However, to get a comprehensive view of Starbucks compliance to socially responsible guidelines, it is necessary to address the company s impact on each stakeholder. The Customer: Who hasn t wondered into a Starbucks location, then left muttering: I can t believe I just spent six dollars for a cup of coffee? Starbucks has built its reputation on serving quality coffee at a high price. It has positioned itself accordingly. (insert graph here) Starbucks originally targeted the affluent, well educatedShow MoreRelatedOperations Management1693 Words   |  7 Pages TABLE OF CONTENTS Introduction Page 2 1. Acme Whistles case study What is the overlap between operations, marketing and product/service development at Acme Whistles? Page 3 2. Oxfam International case study What are the main issues facing Oxfam’s operations managers? Page 4 3. Formule 1 Mwagusi Safari Lodge 3.1 For each hotel, what is the role of technology and the role of operations Page 6 staffRead MoreOperations Managment14673 Words   |  59 Pagesorganization will necessarily call the operations function by this name. (Note that we also use the shorter terms ‘the operation’ and ‘operations’ interchangeably with the ‘operations function’). Operations managers are the people who have particular responsibility for managing some, or all, of the resources which compose the operations function. Again, in some organizations the operations manager could be called by some other name. For example, he or she might be called the ‘ï ¬â€šeet manager’ in a distributionRead MoreExploring Corporate Strategy - Case164366 Words   |  658 Pages22/10/2007 11:54 Page 600 600 Guide to the main focus of cases in the book Introduction to strategy Business environment: general Five forces analysis Capability analysis Corporate governance Stakeholder expectations Social responsibility Culture Competitive strategy Strategic options: directions Corporate-level strategy International strategy Innovation and Entrepreneurship Strategic options: methods Strategy evaluation Strategic management process Organising Resourcing Managing changeRead MoreProject Managment Case Studies214937 Words   |  860 PagesElectrical/Electronic Systems Engineering 388 viii 11 PROJECT RISK MANAGEMENT 401 CONTENTS The Space Shuttle Challenger Disaster 403 The Space Shuttle Columbia Disaster 453 Packer Telecom 460 Luxor Technologies 462 Altex Corporation 466 Acme Corporation 470 12 CONFLICT MANAGEMENT 473 Facilities Scheduling at Mayer Manufacturing 475 Scheduling the Safety Lab 478 Telestar International 480 The Problem with Priorities 482 13 MORALITY AND ETHICS 485 The Tylenol Tragedies Read MoreMarketing Channel44625 Words   |  179 Pagesdistribution channel is more than a collection of firms connected by various flows; it is a(n) ________ in which people and companies interact to accomplish individual, company, and channel goals. A) added value chain B) complex behavioral system C) corporate marketing system D) vertical marketing system E) multichannel system Answer: B Diff: 2 Page Ref: 342 AACSB: Communication Skill: Concept Objective: 12-2 19) An advantage of a channel of distribution over selling direct to consumersRead MoreKellogg Case Book36421 Words   |  146 PagesC (cost) drivers); 3) 4 Cs (company, competitors, customers, collaborators); 4) Profitability (Revenues – Costs = Profits); 5) Value chain analysis; 6) Kotler’s 4 Ps (product, placement, promotion, price); 7) Prof. Nordhielm’s â€Å"The Big Picture† (Corporate Objective, Marketing Objective, Source of Volume, Segmentation Targeting and Positioning, 4Ps, Evaluate); 8) Market segmentation and SPSG (size, profitability, share, growth); 9) Internal/External (internal factors that affect the firm vs. environmental/external

Compare and Contrast Essay on the Mexican and Russian...

S.D. APWH Compare and Contrast Essay on the Mexican and Russian Revolutions In the early 20th century, both Russian and Mexican peoples were both verily dissatisfied with their respective governments. Archaic standards and unjust politics led to unrest and the stirring of the winds of rebellion. With similar political and economic motives, these geographically distanced and different groups of nearly uniform peasantry both stood against their leaders in dynamic revolutions that would eventually end in vastly different sociopolitical positions in their newly claimed nations. The similarities of these two revolutionary bodies were most prominently in their inceptions. To begin with, both the†¦show more content†¦Clearly, in many ways, especially in their beginnings, these two revolutions were verily similar. Conversely, there were also a good number of differences between the two revolutions, and, also on the contrary, the majority of these differences dealt with the results of the revo lution. Firstly, the two nations were geographically quite distanced. Besides the obvious difference this imposes between the two nations, the influence of each respective revolutionary government was based on nearby geographic persuasions respective to each nation. Mexico being adjacent to the U.S., they adopted Democracy, while the Marxist, Eastern-European influence on Russia led them to a Communist government. Second, as just mentioned, the political/economic systems of both nations were verily antipodal. While Mexico adopted free and liberal Democracy and Capitalism to reorganize their faà §ade of a democratic government that was present under Dà ­az, V.I. Lenin incepted a New Economic Policy (the N.E.P.: an ever-so-slightly more liberal Communist economy) and Communist, completely equal and collectivist political ideals to revitalize Russian strength and nationalism in a new Russian era. Finally, a particularly notable difference between the two was their varying levels of p ost-revolutionary social stability. While Lenin’s N.E.P. and Communist reforms did not immediately or completely solve Russia’sShow MoreRelatedCCOT And CC Essay1549 Words   |  7 PagesAfrica Compare and contrast life in foraging societies with life in agricultural societies after the Agricultural Revolution Identify two key changes in early African history that resulted in a new period in the history of the region The Middle East Analyze the political changes in the Middle East from the Agricultural Revolution to 600 c.e. Compare and contrast the basic features of TWO of the following religious systems prior to 600 c.e. Polytheism Judaism Christianity Asia Compare the originsRead MoreKarl Marx : Societal Conflict Based On The Political And Economical Situation3046 Words   |  13 PagesSamantha Chang Art Theory 006 19 December 2014 Essay 1 Marxism is about societal conflicts based on the political and economical situation in society. Karl Marx, the founder of Marixism, believed that communism was the key to a more equal society, because society was divided into two groups the bourgeoisie, the middle class, and the proletariat, the lower class. He was against the ideas of capitalism, which he believed encouraged a system of inequality. Max Weber, a Marxist, explains how â€Å"materialRead MoreChapter 33 – Early 20th Century5648 Words   |  23 Pages | |b. |the Great Depression | |c. |the Russian Revolution | |d. |World War I | ____ 15Read MoreOne Significant Change That Has Occurred in the World Between 1900 and 2005. Explain the Impact This Change Has Made on Our Lives and Why It Is an Important Change.163893 Words   |  656 PagesPHILADELPHIA Temple University Press 1601 North Broad Street Philadelphia, Pennsylvania 19122 www.temple.edu/tempress Copyright  © 2010 by Temple University All rights reserved Published 2010 Library of Congress Cataloging-in-Publication Data Essays on twentieth century history / edited by Michael Peter Adas for the American Historical Association. p. cm.—(Critical perspectives on the past) Includes bibliographical references. ISBN 978-1-4399-0269-1 (cloth : alk. paper)—ISBN 978-1-4399-0270-7Read MoreLangston Hughes Research Paper25309 Words   |  102 PagesHughes, 1933 (Library of Congress) Langston was not ashamed of being a black American. He had already written poems celebrating his heritage. He felt connected to the oppressed brown people of the world and hated his father for mistreating his Mexican employees. 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Part Two Chapter I Free Essays

Fair Comment 7.33 Fair comment on a matter of public interest is not actionable. Charles Arnold-Baker Local Council Administration, Seventh Edition I It rained on Barry Fairbrother’s grave. We will write a custom essay sample on Part Two Chapter I or any similar topic only for you Order Now The ink blurred on the cards. Siobhan’s chunky sunflower head defied the pelting drops, but Mary’s lilies and freesias crumpled, then fell apart. The chrysanthemum oar darkened as it decayed. Rain swelled the river, made streams in the gutters and turned the steep roads into Pagford glossy and treacherous. The windows of the school bus were opaque with condensation; the hanging baskets in the Square became bedraggled, and Samantha Mollison, windscreen wipers on full tilt, suffered a minor collision in the car on the way home from work in the city. A copy of the Yarvil and District Gazette stuck out of Mrs Catherine Weedon’s door in Hope Street for three days, until it became sodden and illegible. Finally, social worker Kay Bawden tugged it out of the letterbox, peered in through the rusty flap and spotted the old lady spread-eagled at the foot of the stairs. A policeman helped break down the front door, and Mrs Weedon was taken away in an ambulance to South West General. Still the rain fell, forcing the sign-painter who had been hired to rename the old shoe shop to postpone the job. It poured for days and into the nights, and the Square was full of hunchbacks in waterproofs, and umbrellas collided on the narrow pavements. Howard Mollison found the gentle patter against the dark window soothing. He sat in the study that had once been his daughter Patricia’s bedroom, and contemplated the email that he had received from the local newspaper. They had decided to run Councillor Fairbrother’s article arguing that the Fields ought to remain with Pagford, but in the interests of balance, they hoped that another councillor might make the case for reassignment in the following issue. Backfired on you, hasn’t it, Fairbrother? thought Howard happily. There you were, thinking you’d have it all your own way †¦ He closed the email and turned instead to the small pile of papers beside him. These were the letters that had come trickling in, requesting an election to fill Barry’s vacant seat. The constitution stated that it required nine applications to enforce a public vote, and he had received ten. He read them over, while his wife’s and his business partner’s voices rose and fell in the kitchen, stripping bare between them the meaty scandal of old Mrs Weedon’s collapse and belated discovery. ‘†¦ don’t walk out on your doctor for nothing, do you? Screaming at the top of her voice, Karen said – ‘ ‘ – saying she’d been given the wrong drugs, yes, I know,’ said Shirley, who considered that she had a monopoly on medical speculation, given that she was a hospital volunteer. ‘They’ll run tests up at the General, I expect.’ ‘I’d be feeling very worried if I were Dr Jawanda.’ ‘She’s probably hoping the Weedons are too ignorant to sue, but that won’t matter if the General finds out it was the wrong medication.’ ‘She’ll be struck off,’ said Maureen with relish. ‘That’s right,’ said Shirley, ‘and I’m afraid a lot of people will feel good riddance. Good riddance.’ Methodically Howard sorted letters into piles. Miles’ completed application forms he set aside on their own. The remaining communications were from fellow Parish Councillors. There were no surprises here; as soon as Parminder had emailed him to tell him that she knew of somebody who was interested in standing for Barry’s seat, he had expected these six to rally round her, demanding an election. Together with Bends-Your-Ear herself, they were the ones he dubbed ‘the Obstreperous Faction’, whose leader had recently fallen. Onto this pile he placed the completed forms of Colin Wall, their chosen candidate. Into a third pile he placed four more letters, which were, likewise, from expected sources: professional complainers of Pagford, known to Howard as perennially dissatisfied and suspicious, all prolific correspondents to the Yarvil and District Gazette. Each had their own obsessive interest in some esoteric local issue, and considered themselves ‘independent minded’; they would be the ones most likely to scream ‘nepotism’ if Miles had been co-opted; but they were among the most anti-Fields people in town. Howard took the last two letters in each hand, weighing them up. One of them was from a woman whom he had never met, who claimed (Howard took nothing for granted) to work at the Bellchapel Addiction Clinic (the fact that she styled herself ‘Ms’ inclined him to believe her). After some hesitation, he placed this on top of Cubby Wall’s application forms. The last letter, unsigned and typed on a word processor, demanded an election in intemperate terms. It had an air of haste and carelessness and was littered with typos. The letter extolled the virtues of Barry Fairbrother and named Miles specifically as ‘unfit to fill his sheos’. Howard wondered whether Miles had a disgruntled client out there who might prove to be an embarrassment. It was good to be forewarned of such potential hazards. However, Howard doubted whether the letter, being anonymous, counted as a vote for an election. He therefore fed it into the little desktop shredder that Shirley had given him for Christmas. How to cite Part Two Chapter I, Essay examples

Civil War Cheat Sheat free essay sample

1850 Compromise of 1850- Fugitive Slave act 1851 Uncle Toms Cabin- 300,000 copies, Harriet Beechen Stows May 1854 Kansas- Nebraska Act- practice popular sovereignty 1855 Bleeding Kansas- fight for slave or free state, 200 died May 1856 Charles Sumner was beat by Southerner Preston Brooks for talking bad about slavery March 6, 1857 Dread Scott Decision- went north with owner then back south. Segregation b. Citizenship c. Equal but separate Keep Maryland to keep Washington dc in the union South economy inflates 000% and north was only 80% John brown raid- help murder slave owners Robert E. Lee homestead Virginia John brown to arm blacks at harpers fairy Emancipation proclamation freed all slaves in rebellion states Whiskey ring- filed false tax reports South had greater ability to produce food Biscuit made of wheat flour was hard tack Lincoln fired McClellan after battle Intimate Vicksburg divided south in two 13th amendment abolishes slavery Scalawags- southerners who worked for republicans and supported reconstruction Anaconda plan makes south run out of supplies Pickets charge is last attack on cemetery ridge Turning points- Gettysburg, bull run 1 and 2, Emancipation proclamation, Intimate, Vicksburg Frederick Douglas is educated free slave Battle of Intimate tells Lincoln to end slavery Military reconstruction act splits it into 5 districts Lincoln through confederate leaders in Maryland in Jail to keep it in the union Hayes ended reconstruction by pulling troops out of south Roger B. We will write a custom essay sample on Civil War Cheat Sheat or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page Tangy was Judge in Dread Scott decision

Huck Finn and Jims Relationship free essay sample

While Huck and Jim travel down the river it becomes apparent that Jim is more of a father figure to Huck than his biological father. Pap teaches the virtues of a life not worth living, while Jim gives Huck the proper fatherly support, compassion, and knowledge for Huck to become a man. Although Huck and Jim come from separate racial backgrounds their time together allows them to surpass their ethnic segregation and become true friends, and family. While Pap acts as an anchor on Hucks heel, Jim opens up a new world for Huck, and becomes his companion and a resource of knowledge. After Huck escapes his father and the sivilized society he encounters Jim, Miss Watsons runaway slave. While on Jacksons island Jim provides useful fables and simple knowledge that aid Huck, Jims simple ideas offer a greater aid to Huck, than any that Pap had ever given. We will write a custom essay sample on Huck Finn and Jims Relationship or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page After the two set out on the raft Jim attempts to protect Huck by any means he posses. Jim uses his resourcefulness to build a wigwam on the raft and raises it so that the two dont get wet The father son relationship also requires respect and love from the child for the father. Jim is rooted in the deepest corners of Hucks heart. Throughout the story we see Hucks compassion for the man. Be it when a rattle snake bites Jim, and Huck nurses him back to life, or when Huck is being interrogated about who his raft companion is; Huck feels it necessary to protect and aid Jim on their journey Pap is the semblance of a poor father; he drinks, scams, and beats his own son. This forces Huck to seek a new father figure. He finds the necessary combination of respect, love, and protection in Jim. Although Jim is not book smart, he maintains the simple values that Huck needs. Their relationship resembles that of a father and son, they both go to great lengths to protect one another and seek each others approval. Huck has no true father but after spending time with Jim and realizing his true qualities he holds a closer bond to Jim than any other male figure he has encountered. Although Hucks bonds to his biological father are severed, by chapter 18, hes discovering a better father in Jim.

The Count of Monte Cristo essays

The Count of Monte Cristo essays The theme of The Count of Monte Cristo, is one of vengeance, forgiveness, and power. The Count of Monte Cristo, is a story of revenge, and forgiveness all in one. This is a story of extreme revenge. The main Character Dante goes to great lengths so that he can avenge his enemies. He realizes at the end that forgiveness is the answer, and that revenge just causes tragedy. Dante is the character that embodies revenge and will change his beliefs many times. Vengeance is the overpowering theme of The Count of Monte Cristo. The story starts out with a young man Dante, he is a naive man that is in love. His life is going great until his friends betray him. He is wrongfully imprisoned for having contact with Napoleon Bonaparte. He is then taken to the Chateau dlf, a prison on an island. Dante spends 14 years there, in this time he meets Abbe Faria, who is a major influence on Dante. Abbe is the man that explains to Dante how he was imprisoned. After he tells Dante this he realizes that he has made a mistake, because now Dante wants revenge. Faria says I regret now, said he, having helped you in your late inquiries, or having given you the information I did. Why so? inquired Dants. Because it has instilled a new passion in your heart-that of vengeance. (pg. ) From this moment on Dante is starting to change from a carefree loving man to man filled with anger and vengeance. Faria was a priest and is very good at predicting human nature, al though Dante is not consumed with anger and vengeance yet he predicts that he will be. Faria helps Dante by telling him about the treasure that is hidden on an island from the Spada family. He also tells Dante how to escape. When Faria dies, Dante escapes when they throw the body sack into the sea. He then goes to look for the treasure that Faria has told him about. He realizes that with the treasure he can be a very powerful man a...

Health Law Essay Example | Topics and Well Written Essays - 750 words

Health Law - Essay Example The trained professional becomes the administrator of the hospital who is responsible to run administrative matters of the hospital. The administrator not only supervises administrative matters but also takes steps to improve the medical staff’s performance. One of the major responsibilities of an administrator is to ensure the delivery of high quality care and treatment to the patients. â€Å"Additionally, they control the day-to-day operations of the hospital, making sure patient care is being met in compliance with state standards and hospital policies† (MacKenzie, n.d.). It is also true that the administrator of a hospital is legally accountable for the quality of care being delivered to the patients. The reason is that the administrator is the main decision-making authority within a healthcare facility. All employees of a hospital, which include doctors, nurses, and paramedical staff, are required to follow the directions of the administrator. Therefore, an adminis trator is responsible for improving patient care, as well as the performance of the medical staff. Answer No: 3 I accept this statement because provision of privileges and fringe benefits to the licensed or board certified physicians depends on approval of administrators of the hospitals. All licensed or board certified physicians have the right to obtain the privileges, however, the final decision regarding provision of these rights depend on the policy set either by the administrator or by the medical chief officer of the hospital. Administrators make the policies to run different matters of the hospital. They are the bodies who decide whether they should give the right of obtaining the privileges to physicians or not. Provision of privileges to physicians is dependent on the policies and philosophy of the board of directors (Joson, 2003). They grant the privileges after analyzing the financial conditions of their organizations. Sometimes, they give this right to physicians and so metimes, they limit the provision of medical staff privileges to some specific privileges. When the administrator or chief medical officer limits the provision of privileges, physicians can choose to contact the courts, which are often employed to uphold and ensure the provision of all those privileges to the physicians that a government hospital provides to their physicians. For example, if the administration of a hospital does not provide a suitable service structure to the physicians, the physicians can contact the court to get the desired service structure. Similarly, physicians can go to court to obtain the allowances and other benefits. Summing it up, I would say that obtaining the privileges is the right of all physicians working in private hospitals and they can contact the court to obtain those privileges. Answer No: 4 In the context of medical liability, the term ‘standard of care’ refers to the level of care that the medical professionals need to provide to t heir patients. â€Å"A standard of care is a formal diagnostic and treatment process a doctor will follow for a patient with a certain set of symptoms or a specific illness† (Torrey, 2008). Medical professionals need to provide a set level of care to the patients in order to meet the standard of care. The standard of care in a hospital is same for every medical professional working in the hospital. All healthcare professionals need

Invitro Fertilization Essay Example | Topics and Well Written Essays - 1500 words

Invitro Fertilization - Essay Example There is no other life experience matching the birth of a baby in importance and significance. It is usually a devastating experience when couples wishing to start a family realize that they have to contend with fertility problems. For many such couples, in vitro fertilization has been a preferred solution as it gives them hopes of having their own child (Anderson, Haimovici, Ginsburg, Schust &Wayne, 2007). The first in vitro procedure that was successful was carried out in 1977 and thousands of happy and healthy children have been born each year since then. Infertility is a couples’ inability to have a kid or become pregnant with regardless of the cause after the duration of one year of having unprotected sex using no birth control methods. Infertility affects about six million people in the United States of America which accumulates to about ten percent of men and women of reproductive age. New and advanced technologies that help women become pregnant are in vitro fertilization (IVF), gamete intrafallopian transfer, zygote intrafallopian transfer, subzonal sperm injection, partial zona dissection, embryo cryopreservation and intracytoplasmic sperm injection among others. Assisted reproductive technology is generally accepted treatment for infertile women suffering from endometriosis. Presence of an ovarian endometrial cyst works towards the reduction of the quality of oocytes. The surgical resection of endometrioma reduces the ovarian reserve for ovarian stimulation by exogenous gonadotropins. In vitro fertilization is a process whereby the ova is removed from a woman’s body, fertilized in the laboratory with her partner’s sperm and returned to her uterus with hopes of fostering pregnancy. Some practitioners use in vitro fertility combined with pre implantation genetic diagnosis as a treatment for recurring

Undergraduate Research Proposal Example | Topics and Well Written Essays - 500 words

Undergraduate - Research Proposal Example While looking at evolution of mammals, keen focus will be set on the GSD, (Genetic Sex Determination). The purpose of this research is to dig deeper into the behavior of the conserved sex determination genes in mammals. By investigating on this, findings could be used to develop an evolution pathway. This way, analysis on patterns of the mammal and birds gene development can be determined. I have decided to use an approach that investigates every sex-determination gene in the different species. Comparisons and behavior relations are observed to determine where each gene differs from each other (Haag & Doty, 3). The project will first proceed by gene collection. Types of the collected genes will go further into the different sex determination genes. For instance, while studying the genes involved in the sex determination process, the somatics will be studied different from the germ-line, focusing on the behavior of each under its classification. Study of these genes will be conducted for mammals and birds and chosen vertebrates of interest. For the vertebrates, the master genes for the sex determinants must be identified. In most of the mammals these genes are indicated in the Y-chromosomes. Alongside this, the NM accession number is to be determined and the knowledge of the longest transcript. This way a sex determining loci can be observed. A complete nucleotide has significant impact on the study of evolutionary impact of sequential pathways. DNA sequences tend to have information about the background of a certain species’ gene. Study on the rate of variations in genomes and relation to environment and population helps to draw a conclusion on the relation between the gene sequences and their evolution. So as to effectively analyze the sequence alignments for quality control, analysis of the palms would be conducted. This type of analysis enables one to determine the protein

Single Molecule Magnets and Single Chain Magnets Analysis

Single Molecule Magnets and Single Chain Magnets Analysis The structures and magnetic properties: molecular nanomagnets phenolic oxime complexes GUAN Shengyang Table of Contents (Jump to) 1 Introduction 1.1 Research background 1.2 Introduction to nanomagnets 1.2.1 Single molecule magnet 1.2.2 Single Chain magnet (magnetic nanowires) 1.3 Structure of phenolic oxime and complexes 2 Researches 2.1 Iron complex 2.2 Manganese complexes 2.3 Complex containing cobalt and sodium ions 2.4 Complex containing lanthanide 3 Conclusion 4 Bibliography Abstract The basic concepts needed to understand and model singlechain magnets will also be reviewed. 1 Introduction 1.1 Research background The researches on molecular nanomagnets began from 1990s, when the first single molecule magnet (SMM) [Mn12O12(O2CPh)16(H2O)4 was researched by Christougroup of University of Florida. [GS1]This mixed-valent manganese complex was found to have an abnormal high spin ground state of S=10[GS2] and highest blocking temperature (below which temperature could the nanomagnets show magnetic properties) in its family ([Mn12O12(O2CR)16(H2O)4], R = various). A large number of SMMs have been reported since then. These[GS3] kind of complexes display the classical property of magnetization hysteresis[GS4] and quantum properties of quantum tunnelling of the magnetization (QTM). These initial discoveries provide a molecular approach to nano-scale magnetism. Following investigation of single molecule magnets (SMMs) and single chain magnets (SCMs) explorers their potential applications in high-density information storage[GS5], quantum computing[GS6], magnetic refrigeration [GS7]and so on. However, to date, nanomagnets discovered have very low blocking temperature (TB). So it is very important to choose appropriate chelate ligands and corresponding metal centres to construct a proper complex with properties to improve blocking temperature (TB) for practical application. Phenolic oxime is a family of compounds with generic structure shown in Figure 1. The phenolate and oxime function groups could form intramolecular hydrogen bonding with its neighbour. These hydrogen bonding resulting in strong coordination effect on metal ions. Such property makes phenolic oxime a good extractant for copper[GS8] in mining industry. Detailed discussion of the phenolic oxime complex structure will be introduced in SECTION 1.3 . Figure 1 general structure of phenolic oxime In this review, knowledge of nanomagnets will be introduced firstly to provide an overview of this field. Then the structure and magnetic properties of compounds with phenolic oxime ligand will be introduced. New techniques applied in synthesis will also be included. It is hoped that this review could be used to assess the potential of phenolic oxime ligand in high performance nanomagnets. 1.2 Introduction to nanomagnets 1.2.1 Single molecule magnet It is helpful to describe the basic theory of SMM with an example. The first single molecule magnet (SMM) [Mn12O12(O2CCH3 )16(H2O) 4] 4H2O ·2CH3CO2H[GS9] was determined to have an S=10 ground spin state, which is contributed by the antiferromagnetic interactions between 4 MnIV ions and 8 MnIII ions[GS10]. However, not like normal size magnet, SMM shows slow magnetic relaxation below a characteristic blocking temperature. This phenomenon is explained by the exist of an energy barrier in reorientation process of magnetic moment. Sessoli et.al. confirmed there exists a relatively large zero-field splitting in this molecule by high-field EPR experiments with a CO2 far-infrared laser. This axial zero-field splitting leads to a splitting of the S=10 state into 21 levels: -10 , -9 , -8, -7, -6 , -5†¦0, 1, 2, 3†¦8, 9, 10. Each level is characterized by a spin projection quantum number ms, corresponding potential energy: †¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦ †¦..(1) D:axial zero-field splitting parameter. In [Mn12O12(O2CCH3 )16(H2O) 4] 4H2O ·2CH3CO2H D=-0.5cm-1 Figure 2 Figure 1. PovRay representation of the core of[Mn12O12(O2CCH3 )16(H2O) 4] 4H2O ·2CH3CO2H, showing the relative positions of the MnIV ions (shaded circles), MnIII ions (solid circles), and  µ3-O2 bridges (open circles[GS11]). Figure 3: Plot of potential energy of different spin state versus magnetization direction From Figure 3, it could be known that the splitting of potential energy levels resulting in a potential energy barrier in the process of changing the magnetic moment. For the example SMM, this barrier equals to E(ms=0)-E(ms=à ¢Ã¢â‚¬ Ã¢â‚¬Å¡Ã‚ ±10à ¢Ã¢â‚¬ Ã¢â‚¬Å¡)=100D. Due to the small value of D, this barrier could be easily crossed in room temperature. If sample SMM is magnetized at 1.5K, the magnetic relaxation time becomes too long to measure. When fitted into Arrhenius relationship: †¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦.†¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦(2) The magnetic anisotropy of the SMM is caused by the structure of the eight MnIII ions. Each MnIII ion with in octahedral crystal shows Jahn–Teller distortion. These distortion[GS12] together with spin-orbital interaction give rise to the easy axis type of magnetoanisotropy. To conclude, a typical SMM consists of an inner magnetic core with a surrounding shell of organic ligands. The desired SMM requires well isolated system which exhibit high spin ground state (S) with a high magnetic anisotropy of the easy-axis (Ising) type. The difficulty is: high spin ground state often requests for several nucleuses, but the magnetic orientation of each nuclei tends to obey Maximum Entropy Models. In this way, the highest magnetoanisotropy of a molecule couldn’t be achieved easily. Some researches show that replacing magnetic core with lanthanide[GS13] ions or using single nuclearity spincluster [GS14]could avoid this problem. Their approaches will be discussed in SECTION 2. 1.2.2 Single Chain magnet (magnetic nanowires) While clusters of SMM can be considered as zero dimensional material, it is possible that one dimensional materials such as nanowires exhibit slow magnetic relaxation and hysteresis effects which are not associated with three-dimensional (3D) order. At 1963, Glauber[GS15] predicted one dimension Ising model (easy axial) would show magnetization relaxation under low temperature. Due to insufficient knowledge in this area and stringent conditions required in the synthesis procedure, chemist wasn’t be able to find any evidences to support or against the prediction, until Gatteschi et al successfully synthesis [Co(hfac)2(NITPhOMe[GS16])] in 2001. Figure 4 Structure of NITPhOMe=4†²-methoxy-phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide Figure 5 Drawing of unit cell of[Co(hfac)2(NITPhOMe)2]. Large dark spheres represent the metal ions. Hydrogen, fluorine, and most of the methyl carbon atoms have been omitted for clarity The structure of the SCM consists of Co(hfac)2 and radicals arranged in helices alternately( Figure 5). In this one dimensional structure, the magnetic core (octahedral cobalt(II) centres) has overall S=1/2 and shows easy axis of magnetization in the chain direction[SG17]. Detailed analysis of spectrums could be found in Caneschi’s report in 2001. To conclude, three essential conditions are need for design SCMs: 1) the ratio of the interaction and interactions is very large. 2) the material must behave as a 1D Ising ferro- or ferrimagnet. This requires the building block or the core of the chain have large ground state spin. 3) the interchain interactions should be minimized to avoid the magnetism of the material be associated with three-dimensional (3D) order. This final condition also apply for SMMs. 1.3 Structure of phenolic oxime and complexes Metal complexes with a planar, electronically delocalized structure have proven particularly attractive for development of cooperative electronic properties because of the strong molecule–molecule interactions that can arise from Ï€-stacking of the planar units 2 Researches 2.1 3d nanomagnet Many 3d nanomagnets have been synthesized and researched on since the first SMM was discovered. f hexanuclear MnIII SMMs based on the complex [MnIII6O2(sao)6(O2CH)2(EtOH)4](saoH2=salicylaldoxime[GS18])9-12 Spin Switching via Targeted Structural Distortion 2.2 Iron complex Variation of alkyl groups on the ligand fromt-octyl ton-propyl enabled electronic isolation of the complexes in the crystal structures of M(L1)2contrasting with Ï€-stacking interactions for M(L2)2(M = Ni, Cu). This was evidenced by a one-dimensional antiferromagnetic chain for Cu(L2)2but ideal paramagnetic behaviour for Cu(L1)2down to 1.8 K. 2.3 Complex containing cobalt and sodium ions 2.4 Complex containing lanthanide Although many magnetic transition metal complexes have been synthesised, the temperature required for transition metal complex to exhibit magnetization relaxation (i.e. blocking temperature) is too low. Hence lanthanide metals were introduced to the complex to increase the blocking temperature. 4 Bibliography [GS1]R. Sessoli, H.-L. Tsai, A.R. Schake, S. Wang,  J.B. Vincent, K. Folting, D. Gatteschi, G. Christou,  and D.N. Hendrickson, J. Am. Chem. Soc. 115  (1993) p. 1804. Sessoli, R.; Tsai, H.-L.; Schake, A.R.; Wang, S.; Vincent, J.B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D.N.J. Am. Chem. Soc.1993, 115, 1804-1816.  [GS2]à ¥Ã‚ Ã…’à ¤Ã‚ ¸Ã…  Ãƒ ¦-†¡ [GS3]Resonant magnetization tunnelling in the half-integer-spin single-molecule magnet [PPh4][Mn12O12(O2CEt)16(H2O)4] â€Å"Spin Tweaking† of a High-Spin Molecule: An Mn25Single-Molecule Magnet with anS=61/2 Ground State New Routes to Polymetallic Clusters: Fluoride-Based Tri-, Deca-, and Hexaicosametallic MnIIIClusters and their Magnetic Properties Molecular Cube of ReIIand MnIIThat Exhibits Single-Molecule Magnetism Syntheses, structures and single-molecule magnetic behaviors of two dicubane Mn4complexes [GS4]Macroscopic Measurement of Resonant Magnetization Tunneling in High-Spin Molecules

Experiencing Pain Essay example -- Health, Philosophy, Personal Experi

Most would agree that pain is an emotion we want to avoid; however, experiencing pain has the potential for insight, knowledge, and a new understanding of life that may not have been in realization. Through experiencing or living with pain, a proper understanding of value can perhaps be brought to things that may not have been valued in a pain free life. Because of pain, the true meaning of life, what it is like to live, and the value of oneself and others is to be within one’s control. Pain is a destructive force, yet it can strengthen the mind and the spirit. As stated in Virginia Woolf’s essay on Being Ill, the true beauty of the people and the real beauty of the earth can be seen through the eyes of those who are in pain. Also according to Woolf, pain can lead to spiritual divinity. From my understanding, the power of prayer to some people is not in belief until pain has overtaken the body of oneself or of a loved one. Pain seems to open the eyes of those who have not correctly lived their lives. Small things in life are regularly overlooked due to the busy and determined career oriented lifestyles. The joys of life come through the detail of the small gestures given or received. The golden rule of â€Å"treat others the way you want to be treated,† is important for people who want to lead a happy life. Until he was deathly ill, Ivan Ilyich, the main character in The Death of Ivan Ilyich, never appreciated the small things in life. His focus was narrowed to one topic. â€Å"Ivan made work the center gravity of his life† (50). Before anything else, including his marriage, Ivan’s work and analyzing way of living was of first priority. Neither Ivan nor his friends valued one another. Ivan’s family and friends treated Ivan ... ...ckily, she survived and my passenger and I survived with minor injuries. Not a day goes by where I do not think about what happened, but I know it happened for a reason. Getting through this painful situation made me a stronger willed person. Taking things for granted is what I do not do. I truly value my life and my family’s lives. A life can be taken away at any second. Giving thanks for the joy and love in life is something that needs to be done daily. Material items are replaceable, but what is irreplaceable is a human being. Memories made will last a lifetime, but the physical presence of a loved one will be gone. The best advice is to live life to the fullest and value the sentimental belongings, especially family and friends. Pain is not an ease, but it helps ease the minds of those who are most important with respect and insight to value.